Fertilizers: Potassium and Compounds

Creating a liquid fertilizer Experiment Chemistry 1065 10/09/2012 Introduction The aim of this experiment was to have a liquid fertilizer containing Nitrogen, potassium and daystar each particle had to have 8% mass voice. We were also required to add an additional element, atomic number 12 and it mass piece had to be 1. 5%. At the subvert of the experiment, the pH of our aqueous upshot had to be amid 6. 0 and 7. 0.As a group we predicted that we could non successfully farm the liquid fertilizer with the chemical compounds we were provided with, because round of the compounds would create a precipitate if mixed. As a result we give-cut that it would be take further experimentation of trying different gang of these compounds on small scale to help us successfully create the required fertilizer. This experiment is important because it is necessary to muddle a do fertilizer that is environment friendly and that provides various plants with the nutrients they need to gro w.This experiment was evoke because gave us the chance to see get in the perspective of the scientists who ceaselessly deliver working towards making the best possible fertilizers for plants. Recent attempts by scientists of making the ideal fertilizer have failed because either the fertilizer is not environment friendly or it increases the birth-rate of agricultural pests. In this lab, we created several compound combinations to try and match the compounds in the required fertilizer.Some of our combinations worked, but round failed. We do adjustments to the original information provided to us in order to meet the standards of the required liquid fertilizer, and as a group we tried our best to imply such adjustments through step to the fore our lab reports so that the reader can be more informed astir(predicate) the experiment we did. . Experimental Because our prediction was that some of the provided compounds would not for an aqueous solving, we opinionated to try out som e combinations on small scale to see how they reacted.The compounds we indispensable for these combinations were Potassium carbonate, trisodium phosphate, potassium nitrate, ammonium ion carbonate, sodium phosphate, and sodium nitrate. We also requisite some piss to solve these compounds in. In order to perform a solubility test on the provided compounds we obtained a strong plate, a spatula to add the solid compounds into the thoroughly plate, a beaker full of distilled water, a pipette to add water into the thoroughly plates containing twain different compounds, and a stir rod to stir the mixture.First employ a spatula we took a small measuring rod of K2CO3 and fix in one of the rise on the well plate. Then we took a small sample of Na3PO4 and put it in the same well. development a pipette we took 3ml of distilled water from the beaker and added it into the well containing K2CO3 and Na3PO4. The using a divine guidance rod, we infinitely moved(p) the resolvent f or 1 minute and we observed. Then we took small samples of K2Co3 and NH4Co3 and put them in a scrap well on the well plate. Then we added 3ml of water using a pipette. Using a stirring rod, we mixed the unfreezer continuously for about a minute.Next we took small samples of NaNO3 and NaPO3 and put them in a third well on the well plate. We added some water using a pipette and stirred up the solution. Then we took samples of NaPO3 and KNO3 and put them in a fourth well in the well plate. We added 3 ml of water, stirred the solution and observed. Next we took samples of Na2PO3, K2CO3 and NaNO3 and put them in a fifth well. We added 3ml of water, constantly stirred the solution and observed. We then took samples of Na2PO3, K2CO3 and NaNO3 and put them in a sixth well plate.Then we added 3ml of water and constantly stirred the solution for a minute and observed. through and through eliminating solutions that formed a precipitate we chose the solution containing, Na2PO3, K2CO3 and Na NO3 as the solution that could potentially be our liquid fertilizer because it contained nitrogen, phosphorus and potassium ions. Because we needed nitrogen, phosphorus and potassium to each have an 8% mass division in relation to the total solution, we calculated how much of each compound we needed so that the three required elements could have 8% mass percentage each in 10g of H2O.We calculate the amount of each compound needed by first figuring it in moles and then we converted it to grams. We replaced Na2PO3 with Na3PO4 because Na2PO3 was unavailable. after calculating how much of each compound we needed to make our fertilizer, we decided that we needed a beaker, a scale, weighing paper, pH analyse, graduated cylinder, stirring rod, Magnesium and H2SO4 to neutralize our solution at the end. We started by weighing out 4. 23481g of Na3PO4, 0. 707g of K2CO3, and 5. 8221g NaNO3. Then we poured the weighed compounds into a beaker.We then measured 10ml of distilled water using a gr aduated cylinder. We then poured the 10ml water into the beaker containing our three compounds. Using a stirring rod we stirred the mixture for about three minutes. The compounds did not decompose in water because the ratio of the compounds to the water could not allow the compounds to wholly dissolve in the water. With instructions from our T. A we decided to divide the amount of all the compounds by 10. The new amounts of the compounds were 0. 423481g of Na3PO4, 0. 0707g of K2CO3, and 0. 58221g NaNO3. We then weighed out these new amounts of compounds.We poured them into a new beaker and added 10 ml water. Using a stirring rod, we continuously stirred the solution until the compounds were completely dissolve. Next we got a pH probe to measure the pH of our solution. The pH of our solution needed to be between 6. 0 and 7. 0. We connected the loggerpro software to a laptop and we the pH collect was 12. 43. Since our fertilizer solution was a base we decided to neutralize it using an acid. The acid we chose to use was H2SO4. Using a pipette we added drops of H2SO4 to our fertilizer solution as we monitored the pH of our solution.It took 2. 4ml of H2SO4 to bring the pH of our liquid fertilizer to 6. 75. To make our liquid fertilizer complete we were required to add an additional element, atomic number 12 such that it had a 5% mass percentage. We chose to use the compound magnesium nitrate because it contains a magnesium ion. We calculated that in order for magnesium to have a 5% mass percentage in the solution we needed 3. 05g of Mg (NO3)2. But because we had divided the other compounds in the solution by ten earlier, we had to divide the amount of Mg (NO3)2 paste to keep the same ratio.So after dividing the amount of magnesium needed by 10 we resulted with 0. 305g of Mg. We then weighed 0. 305g of Mg (NO3)2 on a scale and the poured it into the beaker containing our aqueous solution. Using a stirring rod we stirred up the solution until the Mg (NO3)2 was co mpletely dissolved. We then finished the experiment by measuring the last(a) pH of our solution which was 6. 7. Results information 1 Compounds added to 10ml of water Observations KNO3 & NaPO3 When we mixed these cardinal compounds in water, they formed a turbid solution which turned clear after a while.There was some compound left at the female genital organ of the beaker and this was due to experimental error. K2CO3 & NH4CO3 When we mixed these two compounds, they formed a cloudy mixture. One of the compounds looked suspended which meant it did not dissolve. NaNO3 & K2CO3 When we mixed these two compounds, they both dissolved in the water although there was some compound particles left at the bottom of the beaker which was due to experimental error. NaNO3 & NaPO3 When we mixed these two compounds, they formed a precipitate. NaPO3 & KNO3 When we mixed these two compounds, they did not dissolve in water, they formed a precipitate Na2PO3, K2CO3 & NaNO3 When we mixed these thr ee compounds in water, the completely dissolved Data 2 Substance added to 10 ml of water Observation 4. 234g Na3PO4, 0. 707g K2CO3, and 5. 8221g NaNO3 Did not dissolve in water. The amount ratio of compounds was too big to dissolve. 0. 423481g Na3PO4, 0. 0707g K2CO3, and 0. 58221g NaNO3 only dissolved in water and the pH of the resulting solution was 12. 3 1 ml H2SO4 pH of solution dropped to 11. 14 2ml H2SO4 pH of solution dropped to 7. 45 2. 4ml H2SO4 pH dropped to 6. 7 0. 03052 g Mg(NO3)2 Completely dissolved in water and the pH stayed at 6. 7 Calculations Amount of compounds needed. musical note We divided the terminal amount of the compound needed by 10 so that it would dissolve in water. What we need 10g ? 8%= 0. 8 g N, 0. 8g P, 0. 8g K member Calculations Amount of compound so that element has 8% mass percentage Amount of compound so that element has 0. 8% mass percentage Nitrogen 0. g N3- ? (1 mol N2 / 14. 01g/mol N2)= 0. 057mol N20. 57mol N3- ? (101. 96 g/mol NaNO3) 5 . 8221g NaNo3 0. 5221g NaNo3 Potassium 0. 4g K2+ ? (1 mol K2+ / 78. 2g/mol K)= 0. 005115 mol K2+0. 005115 mol K2+ ? (138. 21 g/mol K2CO3) . 707 g K2CO3 0. 0707g K2CO3 Phosphorus 0. 8g P3- ? (1 mol P3-/30. 97g/mol P)= 0. 02583mol P3-0. 02583mol P3- ? (163. 94g/mol Na3PO4) 4. 23481g Na3Po4 0. 0423481g Na3Po4 Note We used 0. 4g of Potassium because there are 2 potassium ions in K2CO3